Triacetoxyperiodinane → HCID 178424467, compound

Participants

Reaction Steps

The title compound was prepared by the procedure of Example 21, step (a) using 4-cyano-1H-imidazole-2-carboxylic acid [2-(4,4-dimethyl-cyclohex-1-enyl)-4-(4-hydroxymethyl-tetrahydro-pyran-4-yl)-phenyl]-amide (as prepared in Example 25, 40.0 mg, 0.0921 mmol) and Dess-Martin periodinane (80.5 mg, 0.184 mmol). The title compound (40 mg, 100%) was obtained as a white solid and used in the next step without further purification. Mass spectrum (ESI, m/z): Calcd. for C25H28N4O3, 433.2 (M+H). found 433.4.

Provenance & Evidence