참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Potassium thiocyanate | HCID 516872 | — |
| 반응물 | Benzyl 1-methylcyclopropane-1-sulfonate | HCID 89618607 | — |
| 용매 | Water 1,2-dimethoxyethane | HCID 18180031 | — |
| 생성물 | Potassium 1-methylcyclopropane-1-sulfonate | HCID 59386313 | 100% |
반응 단계
KSCN (2.48 g, 25.5 mmol) was added to a solution of Benzyl 1-methylcyclopropane-1-sulfonate (4.9 g, 25.5 mmol) in DME/H2O (1:1, 120 mL) and continued stirring at 100° C. for 16 h. Reaction mixture was concentrated under reduced pressure and the residue was washed with n-pentane and dried to afford potassium 1-methylcyclopropane-1-sulfonate (Int-49) (4.44 g, 100% yield) which was used in the next step without further purification.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09394305B2 |
|---|
| 출처 데이터셋 | uspto-grants-2016_07 |
|---|
| ORD ID | ord-259f1bebdb3a401eb8ee465a32542c17 |
|---|
| 출처 메모 | uspto-grants-2016_07 |
|---|
