alpha-Hydroxyacetophenone → HCID 118093827, compound

HRID 1057018Notes

Reaction equation

[Br:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[C:4]([N+:9]([O-:11])=[O:10])[C:3]=1[O:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.O[CH2:20][C:21]([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)=[O:22]>>[Br:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][CH2:20][C:21]([C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)=[O:22])=[C:4]([N+:9]([O-:11])=[O:10])[C:3]=1[O:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1

Participants

Reactant 2

HCID 68490alpha-Hydroxyacetophenone

HCID 118093987HCID 118093987, compound

Product 1

HCID 118093827HCID 118093827, compound

Procedure

This compound was synthesized according to the procedure of Example 76, Step 5, using 4-bromo-2-nitro-3-phenoxyphenol and 2-hydroxy-1-phenylethanone as the starting materials. LCMS calculated for C20H15BrNO5 (M+H)+: m/z=428.0, 430.0. found: 427.9, 429.9.

Workup

customThis compound was synthesized

Sources & evidence

ORD record: ord-c9281eaba1614e4aa9f414ab9927509b
Source dataset: uspto-grants-2016_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09399640B2

Reaction notes

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