1-Bromohexane → HCID 11732181, compound

HRID 1057264Notes

Reaction equation

HRID 1057264 reaction equation
[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[CH2:5][C:4]=2[CH:3]=1.Br[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[Cl:1][C:2]1[CH:14]=[CH:13][C:12]2[C:11]3[C:6](=[CH:7][C:8]([Cl:15])=[CH:9][CH:10]=3)[C:5]([CH2:13][CH2:14][CH2:2][CH2:3][CH2:4][CH3:12])([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[C:4]=2[CH:3]=1

Participants

3

Reactant 2

HCID 81011-BromohexaneHCID 2519872,7-Dichlorofluorene

Product 1

HCID 11732181HCID 11732181, compoundYield 91%

Procedure

2,7-Dichloro-9,9-di(1-hexyl)fluorene is prepared from 2,7-dichlorofluorene and 1-bromohexane following the procedure of Example 1 as colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C. HPLC analysis shows that the sample is 99 percent or greater pure and the spectral data confirms the title structure.

Workup

  1. customas colorless crystals (recrystallized from hexane) in 91 percent yield, melting point 66° C. to 67° C

Sources & evidence

ORD record
ord-29e2d6ce5b5449da9507e55c59374085
Source dataset
uspto-grants-2003_02
Patent number
US06514632B1

Reaction notes

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