HCID 69191203, compound → HCID 69191773, compound

HRID 1057488Notes

Reaction equation

HRID 1057488 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH:10][C:11]([N:13]2[CH2:19][C:18]3[CH:20]=[CH:21][CH:22]=[CH:23][C:17]=3[CH:16]([CH2:24][C:25]([O:27][CH3:28])=[O:26])[CH2:15][CH2:14]2)=[O:12])=[CH:6][CH:5]=1)([O-])=O>CO.[Pd]>[NH2:1][C:4]1[CH:9]=[CH:8][C:7]([NH:10][C:11]([N:13]2[CH2:19][C:18]3[CH:20]=[CH:21][CH:22]=[CH:23][C:17]=3[CH:16]([CH2:24][C:25]([O:27][CH3:28])=[O:26])[CH2:15][CH2:14]2)=[O:12])=[CH:6][CH:5]=1

Participants

4

Reactant 1

HCID 69191203HCID 69191203, compound

Product 1

HCID 69191773HCID 69191773, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

Methyl 2-(2-(N-(4-aminophenyl)carbamoyl)-1H,3H,4H,5H-benzo[e]azapin-5-yl)acetate was prepared by hydrogenation of methyl 2-(2-(N-(4-nitrophenyl)carbamoyl)-1H,3H,4H,5H-benzo[e]azapin-5-yl)acetate with Pd/C in methanol. EI-MS m/z 354 (M+H)+

Sources & evidence

ORD record
ord-6a3ef30462b44136a9cc657ce8dc34eb
Source dataset
uspto-grants-2003_02
Patent number
US06514964B1

Reaction notes

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