Chlorobenzene → HCID 23563831, compound

HRID 1059042Notes

Reaction equation

[C:1]([C:3]([O:6][N:7]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:8]([CH3:14])([CH3:13])[C:9]([NH:11][CH3:12])=[O:10])([CH3:5])[CH3:4])#[N:2].N(C1(C#N)CCCCC1)=N[C:21]1(C#N)[CH2:26]CCC[CH2:22]1.Cl[C:38]1[CH:43]=CC=C[CH:39]=1>>[C:1]([C:3]1([O:6][N:7]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:8]([CH3:14])([CH3:13])[C:9]([NH:11][CH2:12][CH2:39][CH2:38][CH3:43])=[O:10])[CH2:5][CH2:26][CH2:21][CH2:22][CH2:4]1)#[N:2]

Participants

Reactant 3

HCID 7964Chlorobenzene

HCID 749781,1'-Azobis(cyclohexanecarbonitrile)

HCID 22598524HCID 22598524, compound

Product 1

HCID 23563831HCID 23563831, compoundYield 53%

Procedure

The compound is prepared in analogy to compound (201) from the nitroxide (103) and azobis(cyclohexanecarbonitrile) in chlorbenzene at 100°0 C. in 53% yield as colorless oil.

Sources & evidence

ORD record: ord-86d250870f24438d9d528b71648223a9
Source dataset: uspto-grants-2003_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06518326B1

Reaction notes

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