HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Dimethyl-2-imidazolidinone → Cyclododecanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Dimethyl-2-imidazolidinone | HCID 6661 | — |
| Reactant | 13-Oxabicyclo[10.1.0]tridecane | HCID 9248 | — |
| Reactant | Lithium Chloride | HCID 433294 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | Cyclododecanone | HCID 13246 | 94% |
Reaction Steps
For example, German Patent No. 3,744,094 discloses an isomerization of an epoxycyclododecane in the presence of a catalyst consisting of lithium chloride in a reaction medium consisting of N-methylpyrrolidone or N,N′-dimethylethyleneurea to produce cyclododecanone with a yield of 94%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06518461B2 |
| Source dataset | uspto-grants-2003_02 |
| ORD ID | ord-082ddc1f595c4e1280066f849c3977fa |
| Source note | uspto-grants-2003_02 |