3,4-Dimethoxythiophene → 2-n-Dodecyl-2,3-dihydro-thieno[3,4-b][1,4]dioxine

HRID 10615Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 10615
[CH3:1][O:2][C:3]1[C:7]([O:8][CH3:9])=[CH:6][S:5][CH:4]=1.[CH2:10](O)[C@@H:11](O)[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21]CC>>[CH2:21]([CH:1]1[O:2][C:3]2=[CH:4][S:5][CH:6]=[C:7]2[O:8][CH2:9]1)[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH3:10]

Komponenten

3

Edukt 2

HCID 36135013,4-DimethoxythiopheneHCID 24755028(2S)-Tetradecane-1,2-diol

Produkt 1

HCID 219817762-n-Dodecyl-2,3-dihydro-thieno[3,4-b][1,4]dioxine

Versuchsvorschrift

Chiral 2-n-dodecyl-2,3-dihydro-thieno[3,4-b][1,4]dioxine was synthesized by transetherification of 3,4-dimethoxythiophene with (S)-1,2-tetradecanediol and purified to a purity of 98.01% as described in INVENTION EXAMPLE 1. It was characterized by GC-MS and 1H-NMR-spectroscopy, and exhibited a specific rotation of −65° at 25° C. and 436 nm in hexane.

Aufarbeitung

  1. custompurified to a purity of 98.01%
  2. customa specific rotation of −65°
  3. customat 25° C.

Quellen und Nachweise

ORD-Eintrag
ord-1304dd98d8844e43abc758850cf83b9e
Quelldatensatz
uspto-grants-2006_08
Patentnummer
US07094865B2

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