HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl triflate → 2-Methyl-3,4,5-trichloroisothiazolium trifluoromethane sulfonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl triflate | HCID 9526 | — |
| Reactant | Trichloroisothiazole | HCID 12333154 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 2-Methyl-3,4,5-trichloroisothiazolium trifluoromethane sulfonate | HCID 13097181 | 26% |
Reaction Steps
Trichloroisothiazole (9.4 g, 0.05 mol) and 9 ml of methyl trifluoromethane sulfonate were heated at 65° for 30 min. After cooling, ether (150 ml) was added and the solid collected to yield 4.6 g (26%) of product, mp 118-120. Spectral data (NMR and IR) were consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04328347 |
| Source dataset | uspto-grants-1982_05 |
| ORD ID | ord-3529ed79fc524b80985bc1de26d590bd |
| Source note | uspto-grants-1982_05 |