HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trimethyloxonium hexachlorantimonate → 2-Methyl-3,4,5-trichloroisothiazolium hexachloroantimonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trimethyloxonium hexachlorantimonate | HCID 150258 | — |
| Reactant | Trichloroisothiazole | HCID 12333154 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 2-Methyl-3,4,5-trichloroisothiazolium hexachloroantimonate | HCID 16695738 | 73% |
Reaction Steps
Trichloroisothiazole (10 ml) and trimethyloxonium hexachloroantimonate (7.9 g, 0.02 mol) were heated at 90° for 30 min. After cooling ether (150 ml) was added and the solid collected to yield 7.8 g (73%) of product, mp >240. Spectral data (NMR and IR) were consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04328347 |
| Source dataset | uspto-grants-1982_05 |
| ORD ID | ord-1eaf539dd5af4bf89324dab8922549b1 |
| Source note | uspto-grants-1982_05 |