Pentane, 3-chloro-3-methyl- → HCID 20541590, compound

HRID 1065180Notes

Reaction equation

HRID 1065180 reaction equation
[CH3:1][C:2](Cl)([CH2:5][CH3:6])[CH2:3][CH3:4].[CH3:8][CH:9]([CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)[CH2:10][Cl:11]>C(Cl)(Cl)Cl.[Fe](Cl)(Cl)Cl>[CH3:1][C:2]([C:16]1[CH:17]=[CH:18][C:13]([CH2:12][CH:9]([CH3:8])[CH2:10][Cl:11])=[CH:14][CH:15]=1)([CH2:5][CH3:6])[CH2:3][CH3:4]

Participants

5

Reactant 2

HCID 136701Pentane, 3-chloro-3-methyl-HCID 13510156(3-Chloro-2-methylpropyl)benzene

Product 1

HCID 20541590HCID 20541590, compound

Reagents, catalysts & solvents 2

HCID 24380Iron chloride (FeCl3)CatalystHCID 6212ChloroformSolvent

Conditions

Temperature
20 °C

Procedure

365 parts by weight of 1-methyl-1-ethyl-propyl chloride are added dropwise to a mixture of 510 parts by weight of 2-methyl-3-phenyl-propyl chloride and 49 parts by weight of anhydrous iron (III) chloride at 30° C. The resulting mixture is stirred for 8 hours at 50° C. and for 14 hours at room temperature (20° C.). The crude product is poured into ice water and dissolved in CHCl3, the solution is repeatedly washed with water and dried over Na2CO3, the solvent is evaporated and the residue is distilled.

Workup

  1. washthe solution is repeatedly washed with water
  2. dry with materialdried over Na2CO3
  3. customthe solvent is evaporated
  4. distillationthe residue is distilled

Sources & evidence

ORD record
ord-7200ba737f874ed89a2fe2a07cb47fb3
Source dataset
uspto-grants-1982_05
Patent number
US04328380

Reaction notes

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