HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichlorodiphenylsilane → Acetyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichlorodiphenylsilane | HCID 6627 | — |
| Reactant | tert-Butyl acetate | HCID 10908 | — |
| Catalyst | Tetrabutylammonium Bromide | HCID 74236 | — |
| Product | Acetyl chloride | HCID 6367 | — |
| Product | tert-BUTYL CHLORIDE | HCID 10486 | — |
Reaction Steps
Example 1 was repeated using 2.27 g. (9 m mols) of diphenyldichlorosilane, 1.0 g. (8.6 m mols) of t-butylacetate and 0.07 g. of tetrabutylammonium bromide, except that the reaction mass was heated at 200° C. for 3 hours. A 48% conversion to t-butyl chloride and a 15% conversion to CH3COCl was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04329483 |
| Source dataset | uspto-grants-1982_05 |
| ORD ID | ord-2c28beda04ba417a9211df05a134a8ae |
| Source note | uspto-grants-1982_05 |