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HRID1065755

反应详情

EQUATION

反应方程式

HRID 1065755 的结构方程式

REACTANTS

反应物

2
结构：CCOC(CN)OCC
HCID69524

2,2-Diethoxyethanamine

C6H15NO2

结构：CSC(=C[N+](=O)[O-])S(C)=O
HCID54487094

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(CNC(=C[N+](=O)[O-])SC)OCC
HCID71398340

N-(2,2-Diethoxyethyl)-1-(methylsulfanyl)-2-nitroethen-1-amine

C9H18N2O4S

收率 49%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

A solution of aminoacetaldehyde diethylacetal (11 g, 0.08 mol) and 1-nitro-2-methylthio-2-methylsulphinylethylene (15 g, 0.08 mol) in methanol (200 ml) was stirred for 21/2 hours at room temperature. The solvent was removed in vacuo leaving a yellow oily residue which after trituration with propan-2-ol gave 1-nitro-2-methylthio-2-(2,2-diethoxyethylamino)ethylene (9.8, 49%) m.p. 72°-74°.

WORKUP

后处理

  1. customThe solvent was removed in vacuo
  2. customleaving a yellow oily residue which after trituration with propan-2-ol