Dichloromethane → HCID 131722618, compound

HRID 1066449Notes

Reaction equation

HRID 1066449 reaction equation
ClC([CH:4]=[CH:5][SiH3:6])Cl.[CH3:7][S:8][CH3:9].[Cl:10][BH:11][Cl:12].[Cl:13][CH2:14][Cl:15]>>[Cl:13][CH:14]([SiH2:6][CH2:5][CH2:4][B:11]([Cl:12])[Cl:10])[Cl:15].[CH3:7][S:8][CH3:9]

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 12753630HCID 12753630, compoundHCID 57347243HCID 57347243, compound

Product 1

HCID 131722618HCID 131722618, compound

Procedure

20 ml (24.44 g; 0.173 mol) of dichloromethylvinylsilane were dissolved in 10 ml of dichloromethane and 20 ml (25.1 g; 0.173 mol) of dimethyl sulphide-dichloroborane were added dropwise at 0° C. with constant stirring. After 5 h at 0° C., the reaction mixture was heated to room temperature and, after a further 24 h, the solvent was removed under reduced pressure. The yield of [(dichloromethylsilyl)]ethyldi-chloroborane-dimethyl sulphide was quantitative.

Workup

  1. customthe solvent was removed under reduced pressure

Sources & evidence

ORD record
ord-bdbacdc02103420a8b6de99dfc95ee2f
Source dataset
uspto-grants-2001_06
Patent number
US06242626B1

Reaction notes

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