1-(triphenylmethyl)-1H-imidazole-4-carbaldehyde → HCID 178442739, compound

HRID 1067698Notes

Reaction equation

HRID 1067698 reaction equation
[Br-].C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)CCCCCCCC.C1(C(C2C=CC=CC=2)(C2C=CC=CC=2)N2C=C(C=O)N=C2)C=CC=CC=1.[NH:56]1[CH:60]=[C:59]([CH:61]=[CH:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH3:69])[N:58]=[CH:57]1>>[NH:56]1[CH:60]=[C:59]([CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH3:69])[N:58]=[CH:57]1

Participants

4

Reactant 3

HCID 6182331-(triphenylmethyl)-1H-imidazole-4-carbaldehydeHCID 2724864Phosphonium, nonyltriphenyl-, bromide (1:1)HCID 178442738HCID 178442738, compound

Product 1

HCID 178442739HCID 178442739, compound

Procedure

10 mmol of nonyltriphenylphosphonium bromide, 10 mmol of (1-triphenymethyl-1H-imidazol-4-yl)methanal (see Example 51) are treated as described in Example 51. The product of this reaction ((1H-imidazol-4-yl)-1-nonene) is treated as described in Example 52.

Workup

  1. additionis treated

Sources & evidence

ORD record
ord-b3758c5aecab444ea24b6d6d6f598d83
Source dataset
uspto-grants-2001_06
Patent number
US06248765B1

Reaction notes

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