Stannous Chloride → HCID 15549375, compound

Participants

Reaction Steps

To the solution of 3-allyloxy-4-nitrobenzonitrile (5.85 g, 28.68 mmol) in ethanol (30 ml), Tin (II) chloride (32 g, 143.4 mmol) was added. The reaction mixture was stirred at reflux for 4 hours and then was cooled to room temperature. NaHCO3 (aq) was added to pH=7 was achieved. Then the reaction mixture was extracted with ethyl acetate (3×). The combined organic layer was dried over MgSO4, filtered and concentrated under reduced pressure to give desired product (4.5 g, 90%). EI-MS m/z 175 (M+).

Provenance & Evidence