Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-

HRID 1068521Notes

Reaction equation

CN(C)CCN(C)C.[CH2:9](Cl)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[Cl:17][SiH:18]([Cl:20])[Cl:19]>>[CH2:9]([Si:18]([Cl:20])([Cl:19])[Cl:17])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

Reactant 3

HCID 7503Benzyl Chloride

HCID 8037N,N,N',N'-Tetramethylethylenediamine

HCID 24811Trichlorosilane

Product 1

HCID 69863Benzene, [(trichlorosilyl)methyl]-Yield 52%

Procedure

In the same apparatus and procedure as Example 1 above, 0.116 g (1.0 mmol) of N,N,N′,N′-tetramethylethylenediamine, 0.63 g (5.0 mmol) of benzyl chloride, and 3.41 g (25.2 mmol) of trichlorosilane were reacted at 200° C. for 7 hrs. The resulting mixture was distilled to give 0.57 g of benzyltrichlorosilane (yield; 52%).

Workup

distillationThe resulting mixture was distilled

Sources & evidence

ORD record: ord-816df09f590547248715d676c0189914
Source dataset: uspto-grants-2001_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06251057B1

Reaction notes

Loading…