1-Chloro-4-(chloromethyl)benzene → HCID 22463451, compound

Participants

Reaction Steps

In the same apparatus and procedure as Example 1 above, 0.15 g (0.75 mmol) of tri-n-butylphosphine, 1.21 g (7.5 mmol) of 4-chlorobenzyl chloride, and 5.08 g (37.5 mmol) of trichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 1.8 g of (4-Chlorobenzyl)trichlorosilane; H-NMR (CDCl3, ppm):2.93 (s, 2H, —CH2—), 7.29-7.38 (m, 4H, ArH).

Provenance & Evidence