HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Nitrophenylboronic Acid → 3'-Nitro-[1,1'-biphenyl]-3,4-dicarboxylic acid dimethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Nitrophenylboronic Acid | HCID 1677 | — |
| Reactant | 1,2-Dimethyl 4-bromobenzene-1,2-dicarboxylate | HCID 11323262 | — |
| Catalyst | HCID 178420553 | HCID 178420553 | — |
| Product | 3'-Nitro-[1,1'-biphenyl]-3,4-dicarboxylic acid dimethyl ester | HCID 54494187 | — |
Reaction Steps
n.m.r. δ values include 3.93 (s, 3 H), 3.94 (s, 3 H), 7.65 (t, 1 H), 7.78 (dd, 1 H), 7.86 (d, 1 H), 7.92-7.95 (m, 2 H), 8.26 (dd, 1 H), 8.46 (t, 1 H); from dimethyl 4-bromophthalate (1.80 g), tetrakis(triphenylphosphino)palladium(0) (246 mg) and 3-nitrophenylboronic acid (1.3 g)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06251925B1 |
| Source dataset | uspto-grants-2001_06 |
| ORD ID | ord-cec94691f3b644e9bd75da54b2117515 |
| Source note | uspto-grants-2001_06 |