Sodium Acetate → HCID 86752515, compound

HRID 1069137Notes

Reaction equation

HRID 1069137 reaction equation
[CH2:1]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[CH2:14][O:15][C:16]1[CH:23]=[CH:22][C:19]([CH:20]=O)=[CH:18][CH:17]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[Na+].[S:29]1[CH2:35][C:33](=[O:34])[NH:32][C:30]1=[S:31]>C(O)(=O)C>[CH2:1]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[CH2:14][O:15][C:16]1[CH:17]=[CH:18][C:19]([CH:20]=[C:35]2[S:29][C:30](=[S:31])[NH:32][C:33]2=[O:34])=[CH:22][CH:23]=1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

5

Reactant 3

HCID 517045Sodium AcetateHCID 1201546RhodanineHCID 21191272HCID 21191272, compound

Product 1

HCID 86752515HCID 86752515, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Under a nitrogen atmosphere in a round bottom flask 4-[(2-benzylphenyl)methoxy]benzaldehyde (4.5 g, 14.9 mmol), sodium acetate (4.27 g, 52 mmol), and rhodanine (1.98 g, 14.9 mmol) were dissolved in 75 ml of acetic acid. The reaction solution was then heated to reflux and maintained at this temperature for about three days.

Workup

  1. temperatureThe reaction solution was then heated
  2. temperatureto reflux
  3. temperaturemaintained at this temperature for about three days

Sources & evidence

ORD record
ord-a713de7d6cdf445b85b953431cc46e36
Source dataset
uspto-grants-2001_06
Patent number
US06251928B1

Reaction notes

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