1-(Bromomethyl)-4-(trifluoromethyl)benzene → HCID 86757063, compound

HRID 1069433Notes

Reaction equation

HRID 1069433 reaction equation
[CH3:1][C:2]1[N:7]([CH2:8][C:9]([O:11][CH3:12])=[O:10])[C:6](=[O:13])[C:5]([N+:14]([O-:16])=[O:15])=[C:4](OS(C(F)(F)F)(=O)=O)[CH:3]=1.[F:25][C:26]([F:36])([F:35])[C:27]1[CH:32]=[CH:31][C:30]([CH2:33]Br)=[CH:29][CH:28]=1>>[CH3:1][C:2]1[N:7]([CH2:8][C:9]([O:11][CH3:12])=[O:10])[C:6](=[O:13])[C:5]([N+:14]([O-:16])=[O:15])=[C:4]([CH2:33][C:30]2[CH:29]=[CH:28][C:27]([C:26]([F:25])([F:35])[F:36])=[CH:32][CH:31]=2)[CH:3]=1

Participants

3

Reactant 2

HCID 1230621-(Bromomethyl)-4-(trifluoromethyl)benzeneHCID 11079278Methyl 6-methyl-3-nitro-2-oxo-4-[[(trifluoromethyl)sulphonyl]oxy]-1,2-dihydropyridine-1-acetate

Product 1

HCID 86757063HCID 86757063, compound

Procedure

This compound is prepared from 5.58 g (14.9 mmol) of methyl 6-methyl-3-nitro-2-oxo-4-[[(trifluoromethyl)sulphonyl]oxy]-1,2-dihydropyridine-1-acetate and 5 g (20.9 mmol) of [4-(trifluoromethyl)-phenyl]methyl bromide according to the method described in Example 1.5.

Sources & evidence

ORD record
ord-69c38eeee99644278741d6253746eb42
Source dataset
uspto-grants-2001_06
Patent number
US06252082B1

Reaction notes

Loading…