HCID 22393097, compound → HCID 9867177, compound

HRID 1071340Notes

Reaction equation

HRID 1071340 reaction equation
[CH3:1][C:2]1[C:3](/[C:16](/[Si:28]([CH3:31])([CH3:30])[CH3:29])=[CH:17]/[C:18]2[S:22][C:21]([C:23]([O:25]CC)=[O:24])=[CH:20][CH:19]=2)=[CH:4][C:5]2[C:6]([CH3:15])([CH3:14])[CH2:7][CH2:8][C:9]([CH3:13])([CH3:12])[C:10]=2[CH:11]=1.CC1C(/C(/[Si](C)(C)C)=C/S2C=CC=C2C(OCC)=O)=CC2C(C)(C)CCC(C)(C)C=2C=1>>[CH3:1][C:2]1[C:3](/[C:16](/[Si:28]([CH3:29])([CH3:31])[CH3:30])=[CH:17]/[C:18]2[S:22][C:21]([C:23]([OH:25])=[O:24])=[CH:20][CH:19]=2)=[CH:4][C:5]2[C:6]([CH3:15])([CH3:14])[CH2:7][CH2:8][C:9]([CH3:12])([CH3:13])[C:10]=2[CH:11]=1

Participants

3

Reactant 2

HCID 22393097HCID 22393097, compoundHCID 178469109HCID 178469109, compound

Product 1

HCID 9867177HCID 9867177, compound

Procedure

Following General Procedure C, ethyl(Z)-5-[2-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-2-(trimethylsilyl)vinyl]thiophene-2-carboxylate (Compound 15, 0.050 g, 0.11 mmol) was hydrolyzed to give the title compound.

Sources & evidence

ORD record
ord-31f602823dff41b6909503083e749cd6
Source dataset
uspto-grants-2005_06
Patent number
US06906057B1

Reaction notes

Loading…