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HRID1071345

反应详情

EQUATION

反应方程式

HRID 1071345 的结构方程式

REACTANTS

反应物

2
结构：CC(C)(C)c1cc(Br)cc(C(C)(C)C)c1
HCID620136

1-Bromo-3,5-di-tert-butylbenzene

C14H21Br

结构：CC(C)(C)[Si](OCc1ccc(C#C[Si](C)(C)C)cc1)(c1ccccc1)c1ccccc1
HCID10297175

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)c1cc(/C(=C/c2ccc(CO)cc2)[Si](C)(C)C)cc(C(C)(C)C)c1
HCID23382397

未命名化合物

PROCEDURE

实验过程

Following General Procedure A, 4-[(trimethylsilyl)ethynyl]benzyl tert-butyldiphenylsilyl ether and 1-bromo-3,5-Di-tert-butylbenzene (which can be prepared by the procedure described in Komen and Bickel Synth. Commun, 1996, 26, 1693-1698) were coupled to give the title compound (Compound 32). PNMR (300 MHz, CDCl3) δ 7.40 (s, 4H), 7.33 (s, 2H), 7.08 (s, 1H), 7.07 (s, 1H), 4.78 (d, J=5.9 Hz, 1H), 1.41 (s, 18H), 0.00 (s, 9H).

WORKUP

后处理

  1. customcan be prepared by the procedure