HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1072864Generated: October 31, 2026
N-bromobutanimide → Methyl 4-(bromomethyl)-3-nitrobenzoate
https://huagongshe.com/reaction/1072864
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | Methyl 4-methyl-3-nitrobenzoate | HCID 81816 | — |
| Catalyst | Azobisisobutyronitrile | HCID 6547 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | Methyl 4-(bromomethyl)-3-nitrobenzoate | HCID 13399987 | 127.1% |
Reaction Steps
A mixture of methyl 3-nitro-4-methylbenzoate (4.147 g), N-bromo-succinimide (7.12 g) and AIBN (0.40 g) in carbon tetrachloride (30 ml) was stirred at 70° C. for 42 hr. After cooling, the insoluble matter was filtered off and the filtrate was concentrated to give an oil (7.40 g) containing the object compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06911469B2 |
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| Source dataset | uspto-grants-2005_06 |
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| ORD ID | ord-2009f8b6329047329d881d3b06a34e1c |
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| Source note | uspto-grants-2005_06 |
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