HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → Bis(perfluoroalkanoyl)peroxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | Trifluoroacetic anhydride | HCID 9845 | — |
| Reactant | Potassium trifluoroacetate | HCID 23662811 | — |
| Solvent | Trifluoroacetic acid | HCID 6422 | — |
| Product | Bis(perfluoroalkanoyl)peroxide | HCID 11831103 | — |
Reaction Steps
A solution of bis(trifluoroacetyl) peroxide in trifluoroacetic acid was prepared by addition of H2O2 (95%, 1.61 g, 45.0 mmol H2O2) dropwise into a well-stirred solution of potassium trifluoroacetate (6.8 mg, 0.045 mmol) in freshly distilled bis(trifluoroacetic) anhydride (21 g, 100 mmol) at 0° C. A 31% (mol) solution of bis(trifluoroacetyl) peroxide in the trifluoroacetic acid was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06911561B2 |
| Source dataset | uspto-grants-2005_06 |
| ORD ID | ord-81f38a5312cc400fa663bf3bdee0f602 |
| Source note | uspto-grants-2005_06 |