HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromopentane → HCID 14552600, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromopentane | HCID 7890 | — |
| Reactant | Pentane | HCID 8003 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | Ethyl N-[2-(4-hydroxyphenoxy)ethyl]carbamate | HCID 14552586 | — |
| Product | HCID 14552600 | HCID 14552600 | — |
Reaction Steps
In the same manner, ethyl N-{2-(4-hydroxyphenoxy]ethyl}carbamate (1.25 g, 5.5 mmol) and sodium hydride, prewashed with pentane, (0.132 g, 5.5 mmol) are reacted together, followed by addition of 1-methylbutyl bromide. The mixture is heated at 50° for 20 hours, then worked up and purified by prep. TLC to give ethyl N-{2-[4-(1-methylbutoxy)phenoxy]ethyl}carbamate (compound 14, Table A).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04968829 |
| Source dataset | uspto-grants-1990_11 |
| ORD ID | ord-4f1bbf1151ea44b59829c1b0cedf4154 |
| Source note | uspto-grants-1990_11 |