HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1073643Generated: October 29, 2026
Tributylstannane → tetrahydro-2-[[1-[2-(tributylstannyl)-E-ethenyl]nonyl]oxy]-2H-pyran
https://huagongshe.com/reaction/1073643
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | 2-[(1-ethynylnonyl)oxy]tetrahydro-2H-pyran | HCID 12381804 | — |
| Product | tetrahydro-2-[[1-[2-(tributylstannyl)-E-ethenyl]nonyl]oxy]-2H-pyran | HCID 14582853 | — |
Reaction Steps
To 0.05 g (0.19 mmol) of the titled product of Example 8 is added 0.6 ml (0.22mmol) of tri-n-butyltin hydride, and 20 mg of azoisobutyronitrile (AIBN). The reaction mixture was heated at 110° C. for 3 hours, whereupon thin layer chromatography indicated that the reaction was complete, producing the titled product. The product was used without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04970234 |
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| Source dataset | uspto-grants-1990_11 |
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| ORD ID | ord-ae65d1fe49de4d20a03fd654865e3927 |
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| Source note | uspto-grants-1990_11 |
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