HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl bromoacetate → Ethyl [(prop-2-en-1-yl)sulfanyl]acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl bromoacetate | HCID 7748 | — |
| Reactant | Allyl Mercaptan | HCID 13367 | — |
| Reactant | Ethyl phenylthioacetate | HCID 12284387 | — |
| Solvent | Sodium ethoxide | HCID 2723922 | — |
| Product | Ethyl [(prop-2-en-1-yl)sulfanyl]acetate | HCID 12717294 | — |
Reaction Steps
The procedure is as in Example 2 for the preparation of ethyl phenylthioacetate, starting with ethyl bromoacetate (16.7 g), a 2M ethanolic solution of sodium ethylate (50 cc) and allylmercaptan (7.7 cc). After purification by chromatography on a silica column with cyclohexane as eluent, ethyl (allylthio)acetate (3.1 g) is obtained, and is used in the crude state in the subsequent phases.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04971979 |
| Source dataset | uspto-grants-1990_11 |
| ORD ID | ord-91f249cd31034bc2a566a3015ba0d182 |
| Source note | uspto-grants-1990_11 |