HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Xylyl bromide → HCID 53919754, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Xylyl bromide | HCID 12099 | — |
| Reactant | Ethyl Thioglycolate | HCID 12185 | — |
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Reactant | Ethyl (4-methylbenzylthio)acetate | HCID 4107274 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 53919754 | HCID 53919754 | — |
Reaction Steps
The procedure is as in Example 29 for the preparation of ethyl (4-methylbenzylthio)acetate, starting with 3-bromomethyltoluene (15 g), a 2M ethanolic solution of sodium ethylate (44.5 cc) and ethyl 2-mercaptoacetate (9.7 g) in ethanol (100 cc). Ethyl (3-methylbenzylthio)-acetate (14.4 g) is thereby obtained, and is used in the crude state in the subsequent syntheses.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04971979 |
| Source dataset | uspto-grants-1990_11 |
| ORD ID | ord-3a54247639694b469637e856deb431ef |
| Source note | uspto-grants-1990_11 |