Ammonium Chloride → HCID 178441186, compound

Participants

Reaction Conditions

Reaction Steps

A mixture of 3.21 g (0.01 mole) of 4-(3,5-di-t-butylphenoxymethyl)-1-benzenecarbonitrile, 1.95 g (0.03 mole) of sodium azide, 1.60 g (0.03 mole) of ammonium chloride, 0.42 g (0.01 mole) of lithium chloride and 25 ml of dimethylformamide was heated at 120° C. in a stoppered flask for about sixty-four hours. The mixture was poured into 500 ml of water. The resulting precipitate was collected, rinsed with water and recrystallized from ethanol to give 2.7 g of white crystalline 5-{4-[(3,5-di-t-butylphenoxy)methyl]phenyl}tetrazole, m.p. 253°-255° C. Analysis: Calculated for: C22H28N4O: %C, 72.5; %H, 7.7; %N, 15.4; Found: %C, 72.5; %H, 7.9; %N, 15.0.

Provenance & Evidence