3,5-Di-tert-butylphenol → HCID 15067993, compound

HRID 1074281Notes

Reaction equation

Br[CH2:2][CH2:3][CH2:4][CH2:5][C:6]#[N:7].[C:8]([C:12]1[CH:13]=[C:14]([OH:22])[CH:15]=[C:16]([C:18]([CH3:21])([CH3:20])[CH3:19])[CH:17]=1)([CH3:11])([CH3:10])[CH3:9]>>[C:18]([C:16]1[CH:15]=[C:14]([CH:13]=[C:12]([C:8]([CH3:11])([CH3:10])[CH3:9])[CH:17]=1)[O:22][CH2:2][CH2:3][CH2:4][CH2:5][C:6]#[N:7])([CH3:21])([CH3:20])[CH3:19]

Participants

Reactant 2

HCID 708253,5-Di-tert-butylphenol

HCID 794355-Bromopentanenitrile

Product 1

HCID 15067993HCID 15067993, compoundYield 61.9%

Procedure

Using the method of Example 1, 17.8 g (0.11 mole) of 5-bromo-pentanenitrile was reacted with 20.6 g (0.10 mole) of 3,5-di-t-butylphenol to give 17.8 g of white crystalline 5-(3,5-di-t-butylphenoxy)pentanenitrile, m.p. 61°-64° C. Analysis: Calculated for: C19H29NO: %C, 79.4; , %H, 10.2; %N, 4.9; Found: %C, 79.0; %H, 10.3; %N, 5.1.

Sources & evidence

ORD record: ord-242b8ed6306b43248186823e5687271c
Source dataset: uspto-grants-1990_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04973731

Reaction notes

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