HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → Benzenemethanol, 3-phenoxy-, 1-acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | 1-(Bromomethyl)-3-phenoxybenzene | HCID 94544 | — |
| Product | Benzenemethanol, 3-phenoxy-, 1-acetate | HCID 170904 | — |
Reaction Steps
The resulting m-phenoxybenzyl bromide can be easily esterified in a solvent such as acetic acid to produce m-phenoxybenzyl acetate. The product can be easily converted into m-phenoxybenzyl alcohol by a hydrolysis with a base in a solvent such as methanol. In accordance with the aforementioned treatment, m-phenoxybenzylidene dibromide is converted into m-phenoxybenzaldehyde. Thus, m-phenoxybenzyl acetate and m-phenoxybenzaldehyde are produced by the treatment of the mixture of m-phenoxybenzyl bromide and m-phenoxybenzylidene dibromide, m-phenoxybenzyl acetate and m-phenoxybenzaldehyde can be separated from the mixture by a distillation under a reduced pressure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04393246 |
| Source dataset | uspto-grants-1983_07 |
| ORD ID | ord-8692617004444893b299b7b6fb7ae281 |
| Source note | uspto-grants-1983_07 |