HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
3-Phenoxybenzyl alcohol → 3-Phenoxybenzaldehyde
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 3-Phenoxybenzyl alcohol | HCID 26295 | — |
| Edukt | 3-Phenoxybenzaldehyde | HCID 38284 | — |
| Edukt | 1-(Dibromomethyl)-3-phenoxybenzene | HCID 104630 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Produkt | 3-Phenoxybenzaldehyde | HCID 38284 | — |
| Produkt | 1-(Bromomethyl)-3-phenoxybenzene | HCID 94544 | — |
| Produkt | 1-(Dibromomethyl)-3-phenoxybenzene | HCID 104630 | — |
| Produkt | Benzenemethanol, 3-phenoxy-, 1-acetate | HCID 170904 | — |
Reaktionsschritte
The resulting m-phenoxybenzyl bromide can be easily esterified in a solvent such as acetic acid to produce m-phenoxybenzyl acetate. The product can be easily converted into m-phenoxybenzyl alcohol by a hydrolysis with a base in a solvent such as methanol. In accordance with the aforementioned treatment, m-phenoxybenzylidene dibromide is converted into m-phenoxybenzaldehyde. Thus, m-phenoxybenzyl acetate and m-phenoxybenzaldehyde are produced by the treatment of the mixture of m-phenoxybenzyl bromide and m-phenoxybenzylidene dibromide, m-phenoxybenzyl acetate and m-phenoxybenzaldehyde can be separated from the mixture by a distillation under a reduced pressure.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04393246 |
| Quelldatensatz | uspto-grants-1983_07 |
| ORD ID | ord-00e82e20abc54799aa8446b8cdcb0fdd |
| Quellennotiz | uspto-grants-1983_07 |