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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1074988Generated: November 3, 2026

m-Chloroperbenzoic acid → HCID 53891222, compound

https://huagongshe.com/reaction/1074988

Reaction equation

Participants

RoleNameHCIDCharge
Reactantm-Chloroperbenzoic acidHCID 70297—
ReactantCalcium HydroxideHCID 6093208—
ReactantHCID 85977416HCID 85977416—
SolventDichloromethaneHCID 6344—
ProductHCID 53891222HCID 53891222—

Reaction Steps

540 Mg. methyl-10,11-dihydrodibenzo[b,f]thiepin-3-carboxylate is dissolved in 40 cc methylene chloride and m-chloroperbenzoic acid is added in small portions until TLC shows very little starting material left. Excess calcium hydroxide powder is added and the mixture filtered through celite. The organic layer is evaporated and the residue chromatographed on silica gel to afford 570 mg. (94.7%).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04394515
Source datasetuspto-grants-1983_07
ORD IDord-ad4103f10ea74a8c802220ef3b3cecdf
Source noteuspto-grants-1983_07