2-Benzoylbenzoic Acid → HCID 66697425, compound

HRID 1075391Notes

Reaction equation

HRID 1075391 reaction equation
[C:1]([C:9]1[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=1[C:11]([OH:13])=[O:12])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.COC1C=CC(O)=CC=1>>[C:1]([C:9]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:10]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:11]([OH:13])(=[O:12])[C:10]([CH3:14])=[CH2:9]

Participants

3

Reactant 2

HCID 68132-Benzoylbenzoic AcidHCID 90154-Methoxyphenol

Product 1

HCID 66697425HCID 66697425, compound

Procedure

For comparison, a monofunctional methacrylate benzophenone was prepared. 2-benzoylbenzoic acid (113.2 g) and 4-methoxyphenol (0.06 g) were heated to 130° C. in a three-neck flask to melt, then air sparge was applied and glycidyl methacrylate (77.5 g) and benzyltriethylammonium chloride (0.20 g) were added under stirring. The reaction mixture was stirred at 120° C. for 21/2 hrs. A viscous resin was obtained.

Workup

  1. customair sparge
  2. additionglycidyl methacrylate (77.5 g) and benzyltriethylammonium chloride (0.20 g) were added
  3. stirringThe reaction mixture was stirred at 120° C. for 21/2 hrs
  4. customA viscous resin was obtained

Sources & evidence

ORD record
ord-342151b93ac043b28b0353795de9271f
Source dataset
uspto-grants-1999_05
Patent number
US05900472

Reaction notes

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