(4S)-5-(Benzyloxy)-4-(((benzyloxy)carbonyl)amino)-5-oxopentanoic acid → N-[2-(N-Carbobenzoxy-O-benzyl-L-glutamyl-glycyl)-amino-2-deoxy-beta-D-glucopyranosyl]-N-tetradecyl-dodecanamide

HRID 1075594Notes

Reaction equation

HRID 1075594 reaction equation
[NH2:1][CH2:2][C:3]([C@@H:5]1[C@@H:10]([OH:11])[C@H:9]([OH:12])[C@@H:8]([CH2:13][OH:14])[O:7][C@@:6]1([NH2:43])[N:15]([CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])[C:16](=[O:28])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])=[O:4].[C:44]([NH:54][C@H:55]([C:61]([O:63]CC1C=CC=CC=1)=O)[CH2:56][CH2:57][C:58]([OH:60])=[O:59])([O:46][CH2:47][C:48]1[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=1)=[O:45]>>[C:44]([NH:54][C@H:55]([C:61]([NH:1][CH2:2][C:3]([C@@H:5]1[C@@H:10]([OH:11])[C@H:9]([OH:12])[C@@H:8]([CH2:13][OH:14])[O:7][C@@:6]1([NH2:43])[N:15]([CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])[C:16](=[O:28])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])=[O:4])=[O:63])[CH2:56][CH2:57][C:58](=[O:59])[O:60][CH2:47][C:48]1[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=1)([O:46][CH2:47][C:48]1[CH:49]=[CH:50][CH:51]=[CH:52][CH:53]=1)=[O:45]

Participants

3

Reactant 2

HCID 6994031(4S)-5-(Benzyloxy)-4-(((benzyloxy)carbonyl)amino)-5-oxopentanoic acidHCID 131721235N-(2-glycyl-amino-2-deoxy-beta-D-glucopyranosyl)-N-tetradecyl-dodecanamide

Product 1

HCID 131721240N-[2-(N-Carbobenzoxy-O-benzyl-L-glutamyl-glycyl)-amino-2-deoxy-beta-D-glucopyranosyl]-N-tetradecyl-dodecanamide

Procedure

from N-(2-glycyl-amino-2-deoxy-β-D-glucopyranosyl)-N-tetradecyl-dodecanamide and N-carbobenzoxy-O-benzyl-L-glutamic acid.

Sources & evidence

ORD record
ord-d067c026ea054ba9b765cd11560d7b61
Source dataset
uspto-grants-1999_05
Patent number
US05905071

Reaction notes

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