Methylhydrazine → HCID 12582754, compound

HRID 1075896Notes

Reaction equation

HRID 1075896 reaction equation
Cl[C:2]1[N:7]=[N:6][C:5]2[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:4]=2[CH:3]=1.[CH3:14][NH:15][NH2:16]>>[CH3:14][N:15]([C:2]1[N:7]=[N:6][C:5]2[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:4]=2[CH:3]=1)[NH2:16]

Participants

3

Reactant 2

HCID 6061MethylhydrazineHCID 20441588HCID 20441588, compound

Product 1

HCID 12582754HCID 12582754, compound

Procedure

A suspension of 9.8 g of 3-chloro-5,6,7,8,9,10-hexahydrocycloocta[c]pyridazine in 50 cc of methylhydrazine is stirred in an oil bath of 45° for 24 hours. The material dissolves completely during heating. After the reaction is complete, the mixture is evaporated to dryness, and the crude crystalline title compound is recrystallized twice from ether. The title compound has a M.P. of 78°-79° (decomp.).

Workup

  1. dissolutionThe material dissolves completely
  2. temperatureduring heating
  3. customthe mixture is evaporated to dryness
  4. customthe crude crystalline title compound is recrystallized twice from ether

Sources & evidence

ORD record
ord-2cdc284b02204623882d2fff54d6555f
Source dataset
uspto-grants-1976_05
Patent number
US03954754

Reaction notes

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