Methylhydrazine → HCID 12582663, compound

HRID 1075930Notes

Reaction equation

HRID 1075930 reaction equation
[C:1]([N:9]1[CH2:19][CH2:18][C:12]2[N:13]=[N:14][C:15](S)=[CH:16][C:11]=2[CH2:10]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:20][NH:21][NH2:22]>>[C:1]([N:9]1[CH2:19][CH2:18][C:12]2[N:13]=[N:14][C:15]([N:21]([CH3:20])[NH2:22])=[CH:16][C:11]=2[CH2:10]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 6061MethylhydrazineHCID 178519528HCID 178519528, compound

Product 1

HCID 12582663HCID 12582663, compound

Procedure

A solution of 3.4 g of 6-benzoyl-5,6,7,8-tetrahydro-3-mercaptopyrido[4,3-c]pyridazine in 40 cc of methylhydrazine is stirred at a bath temperature of 110° for 11/2 hours. The oil obtained after concentrating the mixture in a vacuum is taken up in absolute ethanol, and the calculated amount of gentisic acid is added. After standing for some time the crystalline bisgentisinate of the title compound is obtained. M.P. 166°-168° (decomp.).

Workup

  1. customThe oil obtained
  2. concentrationafter concentrating the mixture in a vacuum
  3. additionthe calculated amount of gentisic acid is added
  4. customis obtained

Sources & evidence

ORD record
ord-fb60c9f91cac448ca2feea80af9814d7
Source dataset
uspto-grants-1976_05
Patent number
US03954754

Reaction notes

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