Styrene → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 1076115Notes

Reaction equation

HRID 1076115 reaction equation
[C:1](#[N:4])[CH:2]=[CH2:3].[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>>[C:1](#[N:4])[CH:2]=[CH2:3].[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1

Participants

3

Reactant 2

HCID 7501StyreneHCID 7855Acrylonitrile

Product 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)

Procedure

The addition of the monomer-chain transfer solution prepared by adding 1.65 parts of Carlisle Q-43 to 66.0 parts acrylonitrile and 22.0 parts styrene was begun immediately, and pumping was conducted lineraly over a period of four hours. The reaction was continued for an additional 45 minutes and was terminated by the addition of 0.01 part Naugard BHT. The temperature was held at 70°C while the unreacted monomers were removed under a vacuum of 20 inches Hg. The total solids content of the resulting latex was 29.5%. The latex was coagulated in 11/2 volumes of water, heated to 88°-90°C and containing 3 grams Al2 (SO4)3.18H2O per hundred grams of resin solids.

Workup

  1. additionThe addition of the monomer-chain transfer solution
  2. customprepared
  3. waitThe reaction was continued for an additional 45 minutes
  4. customwas terminated by the addition of 0.01 part Naugard BHT
  5. customwas held at 70°C while the unreacted monomers
  6. customwere removed under a vacuum of 20 inches Hg
  7. temperatureheated to 88°-90°C
  8. additioncontaining 3 grams Al2 (SO4)3.18H2O per hundred grams of resin solids

Sources & evidence

ORD record
ord-884644856f774248948b16e2d037b9b9
Source dataset
uspto-grants-1976_05
Patent number
US03954913

Reaction notes

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