Chlorine → HCID 21539983, compound

HRID 1076284Notes

Reaction equation

HRID 1076284 reaction equation
[CH3:1][C:2]1([NH:8][C:9]([NH2:11])=[O:10])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.[Cl:12]Cl>O>[Cl:12][NH:11][C:9]([NH:8][C:2]1([CH3:1])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1)=[O:10]

Participants

4

Reactant 2

HCID 24526ChlorineHCID 199098Urea, (1-methylcyclohexyl)-

Product 1

HCID 21539983HCID 21539983, compoundYield 66%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
15 °C

Procedure

To a rapidly stirred slurry of 7.5 g (.048m) of N-(1-methylcyclohexyl)urea in 75 ml. water at 15°C was added 3.36g. (.048 m) of chlorine at 0.5 g/minute. The reaction mixture was stirred an additional 1/2 hour at 15°C and filtered. The filter cake was washed with cold water until free of acid and air dried overnight. The white solid weighed 6.0 g (66% yield) and contained 18.9% active chlorine (calculated value for 1-chloro-3-(1-methylcyclohexyl)urea = 18.5% active chlorine).

Workup

  1. filtrationfiltered
  2. washThe filter cake was washed with cold water until free of acid and air
  3. customdried overnight

Sources & evidence

ORD record
ord-c11a3fedac9845ce814ace525dfc7c47
Source dataset
uspto-grants-1976_05
Patent number
US03956366

Reaction notes

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