Sodium Methoxide → HCID 68144007, compound

HRID 1076347Notes

Reaction equation

HRID 1076347 reaction equation
[C:1]([C:3]1[CH:4]=[C:5]2[C:9](=[CH:10][CH:11]=1)[C:8](=[CH:12][C:13]1[CH:18]=[CH:17][C:16]([S:19]([CH3:21])=[O:20])=[CH:15][CH:14]=1)[C:7]([CH3:22])=[C:6]2[CH2:23][C:24]([OH:26])=[O:25])#[N:2].C[O-].[Na+:29]>CO>[C:1]([C:3]1[CH:4]=[C:5]2[C:9](=[CH:10][CH:11]=1)[C:8](=[CH:12][C:13]1[CH:18]=[CH:17][C:16]([S:19]([CH3:21])=[O:20])=[CH:15][CH:14]=1)[C:7]([CH3:22])=[C:6]2[CH2:23][C:24]([O-:26])=[O:25])#[N:2].[Na+:29]

Participants

4

Reactant 2

HCID 10942334Sodium MethoxideHCID 54562088HCID 54562088, compound

Product 1

HCID 68144007HCID 68144007, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

5-Cyano-2-methyl-1-(p-methylsulfinylbenzylidene)-3-indenylacetic acid (1.6 g.) in methanol (10 ml.) is added to a solution of sodium methoxide (0.27 g.) in methanol (5 ml.). The reaction mixture is stirred for 20 minutes and evaporated to dryness to yield sodium 5-cyano-2-methyl-1-(p-methylsulfinylbenzylidene)-3-indenylacetate.

Workup

  1. customevaporated to dryness

Sources & evidence

ORD record
ord-4d6464d12d24474fa4aa7ab3de913712
Source dataset
uspto-grants-1976_05
Patent number
US03956363

Reaction notes

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