Acrylonitrile → HCID 131710200, compound

HRID 1076387Notes

Reaction equation

HRID 1076387 reaction equation
[O:1]1[CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:2]1.[NH2:12][CH2:13][CH2:14][NH:15][CH2:16][CH2:17][NH:18][CH2:19][CH2:20][NH:21][CH2:22][CH2:23][NH2:24].[C:25](#[N:28])[CH:26]=[CH2:27]>>[C:25]([CH2:26][CH2:27][N:24]([CH2:27][CH2:26][C:25]#[N:28])[CH2:23][CH2:22][N:21]([CH2:2][CH:3]([OH:1])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:20][CH2:19][NH:18][CH2:17][CH2:16][N:15]([CH2:2][CH:3]([OH:1])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:14][CH2:13][NH2:12])#[N:28]

Participants

4

Reactant 3

HCID 7855AcrylonitrileHCID 8197TetraethylenepentamineHCID 169931,2-Epoxydecane

Product 1

HCID 131710200HCID 131710200, compound

Procedure

The oily reaction products from 2 moles of epoxy decane and 1 mole of tetraethylene pentamine (52.7 gms, 0.1 mole) is heated at 70°C as in the preceding example with 0.2 moles (10.6 gms) of acrylonitrile until refluxing ceases and for one hour additional. The product is a thick oil with cyano group present and decreased secondary amine shown by infrared examination.

Workup

  1. temperatureuntil refluxing ceases

Sources & evidence

ORD record
ord-a3859d62cc014c11af6d353067eaeab1
Source dataset
uspto-grants-1976_05
Patent number
US03956502

Reaction notes

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