HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl isocyanate → 4-(Allylcarbamoyloximino)-5-methyl-1,3-oxathiolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl isocyanate | HCID 15123 | — |
| Reactant | N-(5-Methyl-1,3-oxathiolan-4-ylidene)hydroxylamine | HCID 71364792 | — |
| Catalyst | Diethyl Ether | HCID 3283 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | 4-(Allylcarbamoyloximino)-5-methyl-1,3-oxathiolane | HCID 171336 | — |
Reaction Steps
A quantity of 3 ml of allyl isocyanate was caused to react with 3 grams of 4-oximino-5-methyl-1,3-oxathiolane dissolved in 50 ml of ether containing 2 drops of triethylamine over a period of 20 hours at room temperature. Conventional workup and recrystallization from isopropyl ether afforded 3 grams of product, mp 66.0°-67.5°, structure confirmed by spectral analysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03956500 |
| Source dataset | uspto-grants-1976_05 |
| ORD ID | ord-b70d4e6f4369405491150e82c996e66a |
| Source note | uspto-grants-1976_05 |