HuagongsheHuagongshe Chemistry Print Report · For research reference only
Styrene → Benzene, ethenyl-, polymer with 1,3-butadiene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Styrene | HCID 7501 | — |
| Reactant | 1,3-Butadiene | HCID 7845 | — |
| Reactant | 1,2-Diethenylbenzene | HCID 66666 | — |
| Reactant | CID 21225536 | HCID 21225536 | — |
| Reactant | Potassium Oleate | HCID 23665571 | — |
| Reactant | Sodium Formaldehyde Sulfoxylate | HCID 23689980 | — |
| Reactant | Diisopropyl benzene hydroperoxide | HCID 57376481 | — |
| Catalyst | Iron | HCID 23925 | — |
| Solvent | Water | HCID 962 | — |
| Product | Benzene, ethenyl-, polymer with 1,3-butadiene | HCID 62697 | — |
Reaction Steps
Into a stainless steel autoclave of 10-liter capacity having an agitator, there were charged 48 parts by weight of butadiene, 12 parts by weight of styrene, 0.6 part by weight of divinyl benzene, and 200 parts by weight of water containing therein 0.9 part by weight of potassium oleate as an emulsifier, 0.12 part by weight of diisopropyl benzene hydroperoxide as a polymerization initiator, and a very small amount of redox assistants such as iron, Rongalite (a trademark for sodium formaldehyde sulfoxylate) and so on, and the emulsion-polymerization was conducted at a temperature of 45°C for 16 hours to obtain a rubber latex of butadiene-styrene copolymer.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03956424 |
| Source dataset | uspto-grants-1976_05 |
| ORD ID | ord-3db30b95820d456199c7a47803c0cc79 |
| Source note | uspto-grants-1976_05 |