Arsenate(1-), hexafluoro-, hydrogen (1:1) → HCID 21536766, compound

HRID 1076450Notes

Reaction equation

HRID 1076450 reaction equation
[Cl-].[CH2:2]([N:4]([CH2:17][CH3:18])[C:5]1[CH:10]=[CH:9][C:8]([N+:11]#[N:12])=[C:7]([C:13]([F:16])([F:15])[F:14])[CH:6]=1)[CH3:3].[F:19][As-:20]([F:25])([F:24])([F:23])([F:22])[F:21].[H+]>>[F:19][As-:20]([F:25])([F:24])([F:23])([F:22])[F:21].[CH2:17]([N:4]([CH2:2][CH3:3])[C:5]1[CH:10]=[CH:9][C:8]([N+:11]#[N:12])=[C:7]([C:13]([F:14])([F:15])[F:16])[CH:6]=1)[CH3:18]

Participants

3

Reactant 2

HCID 167617Arsenate(1-), hexafluoro-, hydrogen (1:1)HCID 21536732HCID 21536732, compound

Product 1

HCID 21536766HCID 21536766, compoundYield 99%

Procedure

4-Diethylamino-2-trifluoromethylbenzenediazonium hexafluoroarsenate was prepared by reacting 4-diethylamino-2-trifluoromethylbenzenediazonium chloride with hexafluoroarsenic acid. Yield 99%; Properties after recrystallization from methanol m. 116°-117° (dec.); N found 9.46%, 9.61%, N calculated 9.7%; molar absorptivity at 385 mμ was 36,000.

Workup

  1. customProperties after recrystallization from methanol m

Sources & evidence

ORD record
ord-b85bc81b2655473abfe47bc86d762241
Source dataset
uspto-grants-1976_05
Patent number
US03957489

Reaction notes

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