tert-Butanol → 2-Propanol, 2-[(1,1-dimethylethyl)azo]-

HRID 1076471Notes

Reaction equation

HRID 1076471 reaction equation
[OH-:1].[Na+].[C:3]([N:7]=[N:8][C:9](Cl)([CH3:11])[CH3:10])([CH3:6])([CH3:5])[CH3:4].[C:13]([OH:17])([CH3:16])([CH3:15])C>>[C:3]([N:7]=[N:8][C:9]([OH:17])([CH3:11])[CH3:10])([CH3:6])([CH3:5])[CH3:4].[CH2:9]([N:8]=[N:7][C:3]([OH:1])([CH3:5])[CH3:4])[CH2:15][CH2:13][CH3:16]

Participants

5

Reactant 3

HCID 6386tert-ButanolHCID 14798Sodium HydroxideHCID 1564434955296-56-5

Product 2

HCID 945822-Propanol, 2-[(1,1-dimethylethyl)azo]-HCID 2035683157910-27-7

Procedure

2-t-butylazo-2-hydroxypropane was prepared by reacting aqueous sodium hydroxide and 2-t-butylazo-2-chloropropane in t-butyl alcohol. The 2-butylazo-2-hydroxypropane was isolated by diluting the alcohol solution with water and extracting with pentane.

Sources & evidence

ORD record
ord-21a9322dfc7a4c3abb21e91c6f45d23d
Source dataset
uspto-grants-1976_05
Patent number
US03957750

Reaction notes

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