Propargyl bromide → HCID 53752703, compound

HRID 1076738Notes

Reaction equation

[CH3:1][C:2]([CH2:15][CH2:16][C:17]([CH3:21])=[C:18]([CH3:20])[CH3:19])=[CH:3][CH2:4][O:5][C:6]1[CH:14]=[CH:13][C:9]([C:10]([OH:12])=[O:11])=[CH:8][CH:7]=1.[CH2:22](Br)[C:23]#[CH:24]>>[CH2:24]([O:11][C:10](=[O:12])[C:9]1[CH:8]=[CH:7][C:6]([O:5][CH2:4][CH:3]=[C:2]([CH3:1])[CH2:15][CH2:16][C:17]([CH3:21])=[C:18]([CH3:20])[CH3:19])=[CH:14][CH:13]=1)[C:23]#[CH:22]

Participants

Reactant 2

HCID 7842Propargyl bromide

HCID 53901559HCID 53901559, compound

Product 1

HCID 53752703HCID 53752703, compound

Procedure

By utilizing the procedure of Example 8, by reacting p-[(3,6,7-trimethylocta-2,6-dienyl)oxy]benzoic acid with propargyl bromide, there is obtained p-[(3,6,7-trimethylocta-2,6-dienyl)oxy]benzoic acid propargyl ester; nD24 = 1.5349.

Sources & evidence

ORD record: ord-a346a29073464684b6e8bd5da49204c4
Source dataset: uspto-grants-1976_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03957833

Reaction notes

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