HCID 21442564, compound → HCID 21442587, compound

HRID 1076778Notes

Reaction equation

HRID 1076778 reaction equation
[CH:1]([NH:3][C:4]([CH2:21][CH3:22])([CH2:19][CH3:20])[C:5]1[CH:10]=[CH:9][C:8]([C:11]#[C:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:7][CH:6]=1)=O.[CH:23]([NH:25][C:26]([CH2:44][CH2:45][CH3:46])([CH2:41][CH2:42][CH3:43])[C:27]1[CH:32]=[CH:31][C:30]([C:33]#[C:34][C:35]2[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=2)=[CH:29][CH:28]=1)=O>>[CH2:21]([C:4]([NH:3][CH3:1])([CH2:19][CH3:20])[C:5]1[CH:10]=[CH:9][C:8]([C:11]#[C:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:7][CH:6]=1)[CH3:22].[CH3:23][NH:25][C:26]([CH2:44][CH2:45][CH3:46])([CH2:41][CH2:42][CH3:43])[C:27]1[CH:32]=[CH:31][C:30]([C:33]#[C:34][C:35]2[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=2)=[CH:29][CH:28]=1

Participants

4

Reactant 2

HCID 21442564HCID 21442564, compoundHCID 21442573HCID 21442573, compound

Product 2

HCID 21442587HCID 21442587, compoundHCID 54034861HCID 54034861, compound

Procedure

When the above experiment is repeated using as alternate starting materials either N-formyl-α,α-diethyl-4-(phenylethynyl)-benzylamine or N-formyl-α ,α-di(n-propyl)-4-(phenylethynyl)-benzylamine there is obtained respectively α,α-diethyl-N-methyl-4-(phenylethynyl)-benzylamine or N-methyl-α,α-di(n-propyl)-4-phenylethynyl benzylamine.

Sources & evidence

ORD record
ord-1792c6ce729d48eab61ff0c9a7145910
Source dataset
uspto-grants-1976_05
Patent number
US03957871

Reaction notes

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