HuagongsheHuagongshe Chemistry Print Report · For research reference only
O-Phenylenediamine → Thiophamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | O-Phenylenediamine | HCID 7243 | — |
| Reactant | Methoxycarbonyl isothiocyanate | HCID 552246 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | Thiophamine | HCID 3032830 | — |
Reaction Steps
Methyl 4-(o-aminophenyl)-3-thioallophanate is prepared by dissolving 11.7 parts of methoxycarbonyl isothiocyanate in 50 parts of benzene and adding this to 10.8 parts of o-phenylenediamine in 200 parts of benzene at 10° - 15°C. After stirring for one hour at room temperature, 13.7 parts of methyl 4-(o-aminophenyl)-3-thioallophanate is recovered by filtration, m.p. 187°C.(D).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03958007 |
| Source dataset | uspto-grants-1976_05 |
| ORD ID | ord-5d008e8d7b8740c18c42e130d39d29e1 |
| Source note | uspto-grants-1976_05 |