HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Iodoanisole → HCID 10518841, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Iodoanisole | HCID 69676 | — |
| Reactant | 1,4-Dibromo-2-nitrobenzene | HCID 77004 | — |
| Product | HCID 10518841 | HCID 10518841 | — |
Reaction Steps
2,5-Dibromo-1-nitrobenzene and 4-iodoanisole were reacted under Ullmann conditions to give 4-bromo-4'-methoxy-2-nitrobiphenyl, m.p. 130°-131°C. This was reduced to give 2-amino-4-bromo-4'-methoxybiphenyl, m.p. 128°-130°C., which was subjected to the Schiemann reaction using hydrofluoroboric acid to give the product, b.p. 134°-138°C./0.15mm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03959364 |
| Source dataset | uspto-grants-1976_05 |
| ORD ID | ord-ba3baeee5ea4437b99ce2dfd7253038e |
| Source note | uspto-grants-1976_05 |